I assume this is due to a web limitation:
Discord has system-wide push to talk (I.e. system wide shortcut) only in the electron app, not in the PWA.
With so many Electron apps in the wild these days, it seems like a great opportunity for the standards bodies to comb them for good ideas for greater platform-wide adoption. (What are people doing in Node processes in Electron that would be tough to do in {Service, Web} Workers? What APIs for deeper native integration would be of benefit?)