I believe cans are more easily recyclable, in part because they're so easy to seperate from other trash (using a big magnet).
It's not that recycling aluminum is easier than other materials, it's that making aluminum from raw bauxite is like the above process times ten. The chemicals are even more dangerous, the process management (environmental protection, regulatory compliance, etc) more expensive, and it requires even more energy. As a result, between 1/3 to 2/3 of all aluminum sold in the US comes from recycled materials because of economic reasons.
Plastics recycling is a much more delicate process, requiring all sorts of washing steps and finely controlled relatively low temperatures.