Most higher earners in e.g. tech or professions will be in the 40% band at least, where the true marginal rate is c.49% (40%+2%+13.8% / 113.8%).
The "top" marginal rate is c.53% (45% tax+2% employee NI+13.8% employer NI / 113.8%) although the highest marginal rate comes between £100k and c.£123k as the personal allowance (bottom 0% band) gets withdrawn making the effective rate (40%+50%x40%+2%+13.8% / 113.8%) = c.65%. (And at the very low end of the scale, as benefits get withdrawn the marginal combined rate of tax and benefit withdrawal is also extremely high).
We don't allow joint filing for married couples which is a significant benefit, especially for single earner couples with high earnings, in the USA.
Then we have mandatory minimum private pension contributions (given these all go into a defined contribution scheme, it's just pay by another name), the apprenticeship levy, etc etc.
Overall, I'd say the UK and "high-tax" parts of the USA (California, New York etc) are similarly taxed at least as far as income is concerned.