Does such a human exist? Other than perhaps someone blind from birth who had their sight restored, I don't think you could fine such a person give how conditioned we are to recognize animals, perhaps even on a biological level. Closest I can think of is animals that are camouflaged, and I think we would see many humans making mistakes on those. I've definitely have, especially with regards to insects that look like plants. But those animals specifically evolved to throw off predator detection systems.
It would be similar to a situation where a human, who sees an improbable object for a given environment, reevaluates his initial perception/understanding of that environment. I can't come up with a good example of such a situation, but you get the idea.