Technically, this is not taking advantage of any public information. It is just capturing images of things happening in public. Anyone could set up a camera and capture license plates as they drive through an intersection.
So is it totally fine for a police force to scan license plates at every intersection?
The question is complicated, because the effect on people changes when you do something that is not worrisome on a small scale in an automated way at a large scale. When you add in that the people doing it have a large amount of power over people and it changes it even more.