On the flip side -- remember your total compensation package. If you work a 60+ hour week, that higher salary broken down to an hourly and compared to the 8 and skate 40 hour a week job suddenly isn't so high. Also compare PTO and other benefits, especially considering "unlimited PTO" often offered by many fast paced places is usually a lie. There's often other benefits in big places that aren't directly salary, but pay off in other ways (discounts, better health care, etc.) And there's the added non-financial benefits of lower stress.
There are pretty big cons to the bigger corporate world, B2B, etc., but money isn't as big of a difference as it first appears.