It's mildly unethical at worse, considering he could have happily done profitable leadgen at scale and it would have likely never been caught if he kept quiet.
If I notice a scummy page impersonating Google, I'm gonna alert Google so they can do something about it. (For example add the page to the safebrowsing list)
"Small amount of time"
?!?
And credit should be given to him for educating everyone on this exploit.
You misled people and breached their privacy. This is as simple as it gets, even if it was for an experiment (though leaving the site online in some other form still raises a lot of question marks..).
My advice for you is to perform future experiments locally, not on the web and make sure people participating in your experiment are aware.