Which I think ranks as one of the stupidest decisions the UK has ever made.
Polar orbits, and their relatives, such as sun-synchronous orbits, are useful for various kinds of missions. For example, earth observation missions, because they overfly every point on Earth, and missions where you need a continuous view of the sun, for solar power or observation.
Why? What would happen if one tried?
That's why the US launches from Florida and the Soviets used to launch from Kazakhstan
Ascension would be more likely, given that it has a runway intended as an emergency runway for the Shuttle, and it has a bunch of communications facilities (GCHQ, NASA, ESA, BBC Atlantic relay) as well as US and UK military facilities.
Lets not be silly, as much as brexit was foolish, the UK will still work in the ESA closely and will still be on very good terms with the vast majority of nations on the planet.
ESA is not in the same situation and e.g. Norway is a member of ESA and Canada sits on the ESA council under a Cooperation Agreement.