commute. lunch. bathroom.
that will probably take 60-120 minutes of your day.
driving to clients for meetings. may be billable, may not be.
driving to potential clients for meetings, and having those meetings - not billable.
dealing with incoming calls and emails.
actually trying to market yourself - blogging, or some other content work, or applying for conference speaking, or planning presentations for local groups (tech groups, business meetups, etc).
debugging crap that doesn't work.
dealing with taxes/payroll/accounting/recordkeeping/insurance.
needing time away to deal with life emergencies or other events.
6 billable - as in, solid productive - *consistently - as in, weeks or months at a time - is generally very hard to pull off for most people. You can certainly be 'on the clock' for more, but just as in about any mental job, you'll have ebbs and flows, and some of that time won't be terribly productive.