I think if you could get a good ratio of guys to girls, the yes. It's a very interesting concept and I think Chatroullette only scratched the surface. I will say one thing though, I have never used Chat roullette or any other service because I find talking to someone live to be somewhat stressful. Can you record videos that are not live and watch videos that are prerecorded? I thought I saw that you could, but it wouldn't let me watch any videos til I created one myself.

I think this has a chance of catching on.

You just have to find the right nitch to go after. Is it online dating (listen to the mixergy match.com interview - their key was gaining women's trust)? Do people want to talk face to face before going out on a date? Could it be founders looking for founders? I don't know. But what I do know is that you should find a segment that could benefit from this the most and go after them. Who's pain is the biggest in this area?