If these were system disks from a prototype Amiga, then it makes sense that these pictures came from an early version of Deluxe Paint, and that .pic was some intermediate / temporary / memory-dump type format before they adopted the .iff system.
Given the Amiga was quite different display-wise, a description of the file format would probably be quite instructive in terms of whether it was an Amiga-native data structure or something already existent somehow.