I'm impressed. From what I've read on your blog, you have gathered a massive amount of data. How do you fight spam?
In my experience, I have found Tweet source (web, Tweetdeck, API etc.) to be one of the most effective quality/authenticity indicators.
There is tons of job tweets, but most have "job" in the username and/or app source. Also any app source that contains "bot" or "feed" is most likely safe to ignore.