Every modern IC engine (and the majority of old ones) operates with a pressurized cooling system; they absolutely will not function properly with a leak.
The average operating temperature of engine coolant is around 200F, the only reason it doesn't boil over is because of the aforementioned pressure, which is usually around 15PSI (bringing the boiling point to just above 250F).
The rating on 50/50 antifreeze relies on coolant system pressure, it (ethylene glycol) will boil like water if put on a stove. The key to antifreeze is in its name: anti-freeze. It does raise the boiling point of water a little, but that's just a side benefit and is of no real significance (plain water transfers heat better).
These readily available facts contradict the comment above. The person is certainly trying to make a point, but they seem to have the fundamentals completely wrong.