Kepler conjecture was stated in 1611 and had been unsolved since. Thomas Hales started a project to attack it in 1992. After six years of work, he announced the proof in 1998, in the form of 250 pages of argument and 3 gigabytes of computer calculation. He submitted it to Annals of Mathematics, one of the most prestigious math journal, for review. Reviewers and the author tried valiantly for five years, gave up, and published it in 2003 with a warning that while reviewers were 99% certain, it couldn't be completely reviewed.
Soon after getting this both rejection and acceptance, Thomas Hales announced the plan to formalize his proof to remove any uncertainty. It was enthusiastically received by automated theorem proving community. For a while Thomas Hales "shopped" for the prover tool to use and basically leaders of every significant provers tried to "sell" it to him. He decided on HOL Light, wrote the detailed plan for formalization, and estimated it would take 20 years. He actually carried out this plan, announced the completion in 2014, wrote the paper on formalization, and submitted the formalization paper, with 21 collaborators, in 2015. The formalization paper was published in 2017.
So there's that. The formal proof of Kepler conjecture is at the moment the most significant corpus of formalized mathematics in existence.