> Aligning values isn't the same as matching personalities

This depends on how you define "personality" and "values". Because for example, according to psychological research, personality traits (as defined by the Big 5 model of personality) are strongly correlated with things such as political beliefs (which could be argued is a subset of a person's values at least), and are largely stable over time. So it wouldn't be too much of a stretch to suggest that the more similar the personalities between a couple, the higher the probability of them also having a large set of overlapping "values", however you choose to define them.