We had shows like X-Men which tackled issues like racism and prejudice, Captain Planet which tackled pollution and environmental stewardship, shows like Gargoyles that introduced mythology and Shakespeare and treated kids like intelligent human beings, Animaniacs which introduced a generation to the Vaudeville tradition of humor, The Magic School Bus which taught children all sorts of facts about the world, etc.
I could honestly go on and on but there was just a ton of great content for kids in the 90s (on network television alone!).
Good content is still being made, the parents just have to choose to consume it!
That type of content has never been more accessible (the PBS kids app is great).
I'm kind of sad that BtAS is not on Netflix, though.