OFDM is orthogonal to PSK (hah). PSK is a modulation--a way of representing bits on a carrier wave. Another type of modulation is QAM. OFDM is a way of combining multiple sub-carriers (each modulated with PSK or QAM) into one signal in order to deal with multi-path distortion: https://www.csie.ntu.edu.tw/~hsinmu/courses/_media/wn_11fall....