AC plug to vehicle means you are doing AC > DC conversion which is not 99.75% efficient. So, if this is 93% including AC > DC that's actually fairly good.
I have this picture that eventually all parking structures will be fitted with solar power to charge parked vehicles. (Roads would be even better, of course.)
Of course if you meant something like panels on the side of the road, or roofs, or something like that then that's fine, those installations would just be pretty standard solar panel installations. But covering the road surface itself is just a bad idea that would require a significant engineering effort and massive cost to work to any degree at all.