In a simple service you can start with just a foreign key from EmailIdentity to the Account. This allows multiple email addresses to be tied to a same account and the same account to have multiple authentication methods or identities (Facebook, email). This way you can implement e.g. changing email address by actually adding an email address and verifying it first, before deactivating the old one.
When you start to need e.g. organization accounts (think about services that have both personal and organizational aspects: Facebook with business pages and ad management, StackOverflow with companies), you can either tie the identities or personal Accounts to the organizational accounts, depending on the model you need.
It can be often useful to add Person model to the mix, which models a real person behind multiple identities / accounts, but this depends on your service.