I know that several RDF data stores use PostgreSQL as a backend data store. With new features like better XML support, as well as older features for storing hierarchical data, I am wishing for a plugin or extension for handling RDF with limited (not RDFS or OWL) SPARQL query support. I almost always have PostgreSQL available, and for RDF applications it would be very nice to not have to run a separate service.
I tend to view PostgreSQL as a "Swiss Army knife" and having native RDF support would reinforce that.