LLVM/Clang might look impressive but AFAIK not even Apple is using it to ship production code.Now, see, thats just plain wrong. Apple ships some pretty big products that are built with clang/llvm: Xcode, OpenGL and OpenCL to name a few. And I wouldn't be surprised if parts of iPhone OS4 are built with it, due to [REDACTED due to the NDA].
Plus, you know, MacRuby. Which is built with LLVM and just as fascinating as IronPython is, in terms of integration with a preexisting environment (only the Cocoa/ObjC runtime instead of .NET runtime). And the few people working on that (some of which are Apple employees) are pretty damn smart as well.
Well, if you want to talk about "hardcore compiler guys"...
I'm also going to have to disagree with you on this. Chris Lattner and the rest of the people working on LLVM at Apple are pretty damned smart (and serious) about what they're working on. They might not have as large of a neckbeard as Ken Thompson does, but, that doesn't mean that they should be ignored outright.