Now MBA is this awesome general degree that teaches you a bit of everything - accounting, sales, some business law. This makes you a versatile tool! :D. The question is, do you know how to best serve a startup? What can you do? What do you want to do? How will you make up for your lack of experience in a certain area - can you learn quickly? Adapt?
Many startups these days start out with the core team being engineers - they're looking to build something, so it makes sense. That said, some startups may do well with a gritty MBA who can go out there and talk to tons of people to generate / prove ideas and report back to the engineering team; take care of accounting; HR stuff if need be; etc... basically it means being the CEO from day one without worrying about the title.
Is that what you're looking for or do you just want a cusy desk job as a junior manager? ;)