Back in the 1990s, when I was doing assembly language on the Amiga, Motorola sent me the official 68000 manual for free when I called and asked them. It was a really cool book to have on the shelf and occasionally lead through.
I looked at abebooks.com, and there are Intel books, but I wouldn't know exactly which one would be the reference manual. Anyone got an ISBN?
http://styx.head-crash.de/stuff/intel_manuals.jpg
Now they still have hardcopy, although it's basically just paying for someone else to print and bind the PDFs for you:
Previously discussed here: https://news.ycombinator.com/item?id=10143295
Internet Archive collection (the Intel documents part): https://archive.org/details/bitsavers_intel
Library of Congress reference: https://www.loc.gov/item/lcwa00096459/