No, you couldn't. Suppose $f(x)$ decays like $O(e^{-x})$ and $a_0$ is the constant term in its power series expansion. Then $g(x)=f(x)-a_0$ decays like $O(e^{-x}$ if and only if $f-g$ decays like $O(e^{-x})$, which in turn is equivalent to the condition that $a_0=0$. In other words, you either have $a_0=0$ in the first place (but then you have a circular argument, not a genuine proof), or $g(x)=f(x)-a$ not decaying like $O(e^{-x})$.