I can't quite figure out if PHP is the only language that you can collaborate with and I don't want to start a session to let someone down. Maybe you could update the website or any of the blog posts with this info?
It's super interesting to see how easy it is to learn the basics of a new programming language when you are coding with someone else that already knows it. It's like having a teacher just for you.
In any case, we have removed PHP from the list... everyone hates it haha.
You will eventually want to move to an ELO-ranking like system to make sure the pairs are roughly balanced. Otherwise, there's no way it would be fun for an expert-level C developer to pair with a newbie JavaScript programmer and have to spend the whole time explaining what pointers are, etc.