Although it was ~30 years ago, I recall doing some school homework when we had just learned about prime numbers and factorisation. I remember trying to divide by random primes until I came across a factorisation. It wasn't at all obvious to me (at ~10 years old) that prime factorisations were unique or that they could be found using a simple repetitive algorithm.
It seems obvious now, but only because I've never come across an integer with more than one factorisation. If there were an article on HN tomorrow with the headline 'Integer with more than one prime factorisation found' I wouldn't be able to resist clicking the link.