Interesting to see how well Georgetown does. Figure it's lots of children of legislators following in their parent's footsteps.
It also has an extremely well regarded foreign service program.
Plus if you're already doing political stuff in the city as a professional, the law school is not only the best in the area but one of the best in the country, which makes it a common choice for those in that line of work.
And let's not forget that this is just people affiliated with the university, which could include members of congress who teach classes at the school, not sure what the congressional roster is like right now but for example Madeline Albright teaches a very popular foreign service course.