IRC is often mentioned in regards to slack, but I find Instant Messenger(s) a bit closer in spirit. Did everyone stop using those too, in favor of facebook and slack, etc?
I do think that the Slack homes for user groups and open source projects (the ones set up with auto-invite on Heroku) are direct replacements for "join us on Freenode" invitations.
We've got customers that are doing tens and hundreds of thousands of chats per day across their organizations.