Going rate for humans breaking captchas is like $1/1000 captchas solved. A fully automated service could make some money, sure, but not exactly a killing.
The best I've seen are the "which of these photos show mountains"-type challenges. I'd imagine that solving 5 rounds of those would take too long to make it worthwhile for spammers, but I'd also imagine lots of legitimate users getting irked at going through that to fill out a form.