One big thing to beware of is VAT and VAT MOSS scheme - it's a bit of a nightmare to figure out your way around that. After discussing with accounts and lawyers your best option is to not be VAT registered until you know you're going to exceed the £82k threshold. Again - speak with your own lawyer and accountants on this as everyone's situation is different.
Hope that helps!
TL;DR - https://news.ycombinator.com/item?id=11360598 - Covers company formation (and recommends a couple of accountancy options for the UK)
- https://news.ycombinator.com/item?id=11360651 - Covers Legal advice for US and UK startups.