The list I've gone off of is https://python3wos.appspot.com/. I use python a lot, and only now in late 2015 I might finally use python3 if starting a new project. When I started a new project last year, we used python2.
The biggest hold-out for me was gevent, which was only released 5 months ago. Gunicorn with gevent workers is my preferred stack for running python apps.
If you use protobufs or thrift, those both aren't yet on python3.
The wall of shame currently lists requests as not working on python3, though I think that might be a fluke.
These ones might not be a deal-breaker since you can have a separate environment for infrastructure & app code, but for some reason a lot of the infrastructure tools still haven't updated to python 3 (supervisor, ansible, fabric, graphite).
All together, it adds up to a not-insignificant number of things that aren't yet on python3. And even if nothing you use when you first start a project is python2 only, you have no idea what libraries you might need or want in the future and if those might be python2 only.