cat tmp.png
"Yep that looks like it's right"
git add tmp.png
"Yep that looks like it's right"
git add tmp.png
In short: the time savings introduced by shortening the feedback loop tend to add up. There is a reason why Web developers now use auto-reloading solutions, despite the fact that it saves "just one keystroke" (F5 in this case).
http://superuser.com/questions/246825/open-file-from-the-com...
(I suppose a similar thing could be done on *nix with a suitably modified execlp()/execvp().)
On Linux you should be able to wire up binfmt_misc, the plugin system for execve, to xdg-open.
Then you could just call that external difftool when comparing images:
git difftool --tool img-diff
Just an example.