If that's a correct interpretation, then no, absolutely not. Most engineers (you see this if you sift through linkedin) make far less optimal (I believe) choices than they would by simply picking a Series A/B company backed by a tier one firm like Sequoia/A16Z/Greylock/Benchmark.
And surprisingly, people take very little time to think about what they want, what they care about, what they believe the world needs, what they enjoy, and so on. Doesn't seem like a good idea given they'll/you'll spend 50%+ of your waking hours at work.