What do you mean? The waste is full of nuclear poisons (a technical term, isotopes that stop fission by neutron capture). Reusing it means reprocessing to extract the Plutonium, which is burnable in a reactor (particularly as MOX). The chemistry required for this is pretty messy, and the radioactive environment (fuel from a power station is very 'hot' radioactively speaking) so horrific that you need a fully robotic plant.
This hasn't gone great for the UK, https://en.wikipedia.org/wiki/Thermal_Oxide_Reprocessing_Pla...
But we do now have 112 tonnes of Plutonium as a result of our half a century of reprocessing. Which no one knows what to do with, and is an enormous liability.