Just look at the OP: he left an ostensibly good job to join a YC startup and he's already questioning the founder's behavior and competence. When he starts feeling pressured to work insane hours, or completely loses faith in the founder's sanity and competence, how long do you think it will take him to find a new employer that promises something better?
At the risk of being overly harsh, if you feel you're incapable of making "stuff happen" without sending random emails at 3 am in the morning or acting like you don't have control over your schedule and business or terrorizing your employees into believing that they need to be online at all hours, you're probably out of your depth and should be honest with yourself about your readiness to run a business with employees.
A lot of people in the startup community have deluded themselves into believing that "hard work" is the one and only key to success but by and large, successful businesses are built by doing the right things, not by running around for 18 hours a day like a chicken with its head cut off. Thanks to the funding boom, a lot of chickens with their heads cut off are running companies. Folks like the OP work for them at their own peril.