I purchased a pair of shoes that I needed to return, going back to Italy, and I received a quote from UPS - having entered the weight on the parcel I had received - of around £50. Later, after UPS had picked up the parcel, I noticed they had charged me somewhere in the region of £80-100.
I rang up and they explained that UPS doesn't use normal weight but rather a UPS specific "weight" that also incorporates dimensions (i.e. two items that are different sizes but weigh the same will have different UPS weights).
I looked on the site and they were right - there was some information about it, plus a calculator for working it out. I must have completely missed it. To their credit, they did refund the difference and I only had to pay the original quote, but I do wonder how many other people miss it and end up paying more for their postage.
Here's how to figure out the "billable weight": http://www.ups.com/content/us/en/resources/ship/packaging/di...