2. Used by very popular websites e.g. Twitter, Facebook, Yahoo so you get projects like http://webscalesql.org to utilise.
3. More options for client side tooling although debatable whether these are better than generic options.
4. MySQL Cluster is a more cohesive solution for clustering.
5. The most likely reason: you have bought something that needs it.
Obviously PostgreSQL has plenty of reasons for choosing it over MySQL.