The advanced features allow you to have more than one way to do things, sometimes in a slightly more concise way (I've been tempting to use jsonb type in place of simple many-to-many tables if one of the values are just always be string). It's not that I'm expecting my app to be web scale or anything, but I'd rather not having to redesign everything one a query choke on a million records. And most of the docs tend to be light on performance characteristics.
As performance is one of the most important aspect in database system in general (which I'd say on par with consistency, and way a head of features), it'd be nice to have docs focus more on not just how to use features, but when it shouldn't be used.