The 18F Github contains a lot of interesting work, with reliance on contemporary frameworks and practices (Jekyll seems to be their choice for microsites) https://github.com/18f
I loved 18F's work with overhauling the Federal Register site (https://www.federalregister.gov/)...and even if you think the federal government's data efforts are paltry...then you haven't seen what existed before 2009...which is pretty much nothing. The wide array of data and information that has been machine-readable and public accessible via the Internet is pretty astonishing, and while I doubt that President Obama has made it a point to keep tabs on his IT, whoever has been whispering in his ear has been very effective.
Edit: a cool project I noticed on 18F's github: https://github.com/18f/mirage ...a Django/PostgreSQL project to assist procurement officers in surveying the market for vendors...another 18F repo contains the Chef recipe for its deployment.