That only works if startups fail 50% of the time. If they fail more frequently, a coin flip would be wrong.
The point made in the article is that investing at the odds of a coin flip would be better than investing with incorrect risk assumptions (ie. buying into "particularly bad ideas").
Assume startups fail 90% of the time. 50% of the time your coin comes up tails, and you claim the startup will fail. 50% of the time your coin comes up heads and you claim the startup will succeed.
You guess correctly 0.5 (the chance your coin comes up tails) * 0.9 (the chance the startup fails) + 0.5 (heads) * 0.1 (success) = 0.5 of the time.