I've often thought about opening a bar (or movie) theater where all wireless communications are blocked, to force people to not use their phones.
Obviously I'd put up extremely big and obvious signs stating that, and I'd only be blocking if you were inside my building.
Legal?
EDIT: I wouldn't be blocking anyone from setting up a wi-fi hotspot inside my bar, but comms to the outside world would be blocked using that cool paint, or a Faraday cage of some sort.