DANE as an application of DNSSEC is interesting (and based on the recent string of editorials, contentious as well). Using DANE to constrain CAs could add an additional layer of protection against a rogue CA. Using it as an additional CA could help facilitate moving towards "HTTPS-everywhere".
The takeaway of course in implementing it in any manner is that it is just another layer, not a panacea.
Outside of DANE, there are other applications such as IPSECKEY and SSHFP that have utility.