Python is a prime example of a rotten standard library.
Take urllib/urllib2 (use requests instead), unittest (use py.test or nose), os (too low-level, hence arcane usage) or time as examples (use pytz for anything serious), and of course Tkinter.
Take all of the modules that solve minor/niche tasks that could easily have been put in a seperate library (e.g. wave), that are usually a bad idea to use (e.g. pickle), that contain some copy/pasteable functions the authors deemed useful as comments (itertools), have documented bugs with copy/pasteable workarounds (csv).
Oh, and the way they do exceptions is a mess.
Oh, and don't try to read the Python standard libraries source code. It's ugly.
No, standard libraries should constrain themselves to providing a good foundation for library designers.
(I still like Python, and use it a lot.)
(Since you mentioned Go. One thing that I love about Go is that everything interaction with the underlying OS goes through the syscall package. Also, their designer went for more minimalism. And they didn't have to worry about design mistakes they made 25 years ago. Python is old. I'm not a fan of Gos compatibility promise: it means Go 1 will rot away too. But they're in a much better starting position.)