It's really not fair to compare FLAC vs MP3 to "hi-rez" FLAC vs regular FLAC
There's legitimately some instruments that do not compress well. The harpsichord is a particular example that you should be able to hear the difference on on any sort of decent equipment.
Bur hi-rez vs regular flac is something that I don't think can be really detected by humans. I've gone through and done the Philips golden ears challenge to completion, and have very high end equipment, blind ABX FLAC vs MP3 on a lot of songs I am familiar with, but have never once been able to successfully ABX between a 24/192 flac and a regular one.