I guess the output of the fuel after use is still greenhouse gas, but would this reduce net CO2 emissions?
The problem with fossil fuels is that they transfer old carbon which used to be stored underground into the atmosphere.
This process only uses carbon that is already part of the active carbon cycle, so it is carbon neutral as long as the electricity source is.
However comparing making liquid fuel this way, with drilling refining and shipping gasoline, it may be a great improvement!
i.e. it doesn't matter if you take CO2 out of the surface ocean or the atmosphere. Both will reduce the concentration of CO2 in the atmosphere.