No, there is still an lower limit of 4.37 years to get to alpha-centauri within any frame of reference no matter how much you accelerate within conventional space.
What relativity does, is that if you travel close to speed of light time taken for the trip as measured on ship versus on earth could be different by many orders of magnitude.
edit: Was wrong, as per [0] "This is something many readers don't understand well, so it bears repeating: The journey times as experienced by those on the ship are not limited by the speed of light. Instead what they experience is the planetary reference frame getting relativistic."
[0] http://en.wikipedia.org/wiki/Space_travel_using_constant_acc...