Can the NSA 'tag' a specific user using Tor? If so, wouldn't using Facebook over Tor then provide them with a direct link between your FB identity and your other Tor activity?
A new session can be created by restarting Tor or from the tor indicator if within TAILS.
The reason for this is that it never leaves the Tor network. Traffic from a tor client to a hidden service goes (encrypted) through relays, but never exits. Basically you are entering a validation of the public key when you type in the .onion address, so nobody can tamper with the connection.