Maybe this is an opportunity for a startup -- steal Netflix's DVD rent by mail business and offer a very extensive catalog. Seems like Netflix would be happy to cede that market.
http://www.netflixreview.com/netflix_plans.html
Netflix has already built out great infrastructure for this but clearly didn't find it profitable enough to focus on it. I'd be very hesitant assuming that you've seen a market which they haven't.
Though Amazon might've already locked that market up. Why rent when I can buy for $0.01 + $3.99 shipping?