You'll be less productive, but you'll have more fun when you get to program in language. A good trade off? I don't think so. A few years down the road you'll have to maintain the same project. The honeymoon period is over, and the code base isn't quite as good as you'd like it to be (you designed the project back when you didn't know the language very well, and it shows). You know you could spend a few weeks refactoring, but that would probably introduce bugs and you'll drive the other people in your team crazy if you start renaming methods, and move stuff around just to make the code "nicer". And besides, you'd much rather be programming in the next-nifty-language, because it lets you extend the syntax at runtime and it has a debugger that will let you go back in time.
The bottom line is that when you pick a language that is on the cutting edge of cool right now will no longer be cool a few years from now, but it still won't have any libraries and other essentials. Languages too have to cross the chasm, and they all have to go through a period where they're neither new and exciting nor stable.
If you're serious about software, concentrate on writing something that is reliable as hell and easy to maintain and install. Want a challenge? Write your app in such a way that power can be lost at any point in time without losing any user data. Or (for desktop apps) make sure that the UI -never- hangs, even when the hard drive has to spin up. Software is never done, there are always things you can make better, more fault tolerant, faster. It's not as if we've run out of challenges.
Messing around with unstable languages is a lot of fun. It's educational too. But don't build your business around it. Python/Django and Ruby/Rails are only barely stable enough to work with. Thinking that using Haskell, Clean, IO or Lisp will be a net benefit to productivity is foolish.
(Of course there are obvious exceptions, and that Clojure and Scala use the JVM does make the whole library thing less of an issue. But it's still a big deal.)