Some benchmarks against other graphdbs (but it was with Titan 0.3): http://euranova.eu/upl_docs/publications/an-empirical-compar...
Titan underwent major changes to optimize in-memory operations. Here is some up-to-date info on that: http://thinkaurelius.com/2013/11/24/boutique-graph-data-with...
IIRC, the euranova benchmark doesn't discuss scalability. This post does: http://thinkaurelius.com/2013/05/13/educating-the-planet-wit...